赣南淘锡坑石英脉型钨矿床成矿机制探讨:来自流体包裹体的证据   总被引：1，自引：1，他引：0  

鲁麟  梁婷  任文琴  赵正  刘善宝  陈郑辉 《矿床地质》2018,37(6):1260-1280

赣南地区淘锡坑钨矿床是典型的大型石英脉型钨锡多金属矿床。矿体赋存于震旦系浅变质砂(板)岩,并延伸至深部花岗岩内,按空间产出位置分为内带矿体和外带矿体,包括宝山、西山、烂埂子、枫岭坑4大脉组,矿体产出各不相同,矿物组合也具有明显分带特征。在详细的岩相学研究基础上,文章选择淘锡坑主成矿期石英为研究对象,并与共生黑钨矿作对比,从空间角度开展不同脉组、不同矿体或中段的流体包裹体的对比研究。根据流体包裹体岩相学,石英包裹体类型有H_2O-NaCl型包裹体(Ⅰ型)、H_2O-NaCl-CO_2型包裹体(Ⅱ型)和纯CO_2体系裹体(Ⅲ型)及少量含石盐子晶的多相包裹体,并同时捕获贫CO_2的盐水溶液包裹体和纯CO-2气相包裹体。包裹体显微测温结果显示:内、外带石英脉气液两相的包裹体均具有较宽温度和盐度范围,外带均一温度和盐度w(NaCl_(eq))分别集中于200～220℃、1%～6%,内带均一温度和盐度w(NaCleq)分别集中于100～220℃、3%～7%,流体为中-低盐度、富含CO_2的H_2O-CO_2-NaCl体系,不同脉组不同矿脉之间对比结果均显示出多期成矿的特征。在矿脉形成过程中,流体的成分和温度在内外接触带有明显变化,表明岩体与围岩接触界面是造成淘锡坑矿床内带矿体和外带矿体的成矿条件改变的转折位置,成矿流体在此附近发生CO_2逸失引起相分离的不混溶作用是成矿的主要因素。  相似文献   

秘鲁Don Javier斑岩铜钼矿床流体包裹体特征   总被引：1，自引：1，他引：0  

赵宏军  王可勇  邱瑞照  陈秀法  卢民杰  王军  杨日红 《矿床地质》2018,37(5):1065-1078

Don Javier斑岩铜钼矿床位于南美安第斯成矿带中段,秘鲁中南部-智利北部巨型斑岩铜钼金多金属成矿带上,矿区主要出露Yarabamba超群花岗闪长岩岩基和英安斑岩岩体,矿体呈筒状,主要赋存在英安斑岩体及其围岩中,受NW向断裂构造控制。在野外地质调查的基础上,文章对矿床流体包裹体特征进行研究,并结合矿体产出形态特征,对成矿流体来源及演化进行探讨。对黄铁矿-石英和黄铜矿(辉钼矿)-石英2个成矿阶段的石英流体包裹体研究结果表明,成矿阶段矿石中发育富气相-液相、气液两相及含NaCl子矿物三相3种类型的原生流体包裹体,流体包裹体均一温度为287～499℃,含NaCl子矿物包裹体的盐度w(NaCleq)为30%～42%,密度为1.08～1.21 g/cm3,成矿流体属于中高温、高盐度的NaCl-H_2O体系,为岩浆热液来源的成矿流体。流体包裹体特征还表明,流体的沸腾作用是引起成矿流体中矿质发生沉淀富集的重要成矿机制。  相似文献   

Tectono–Thermal Evolution, Hydrocarbon Filling and Accumulation Phases of the Hari Sag, in the Yingen–Ejinaqi Basin, Inner Mongolia, Northern China     

YANG Peng  REN Zhanli  XIA Bin  TIAN Tao  ZHANG Yong  QI Kai  REN Wenbo 《《地质学报》英文版》2018,92(3):1157-1169

This work restored the erosion thickness of the top surface of each Cretaceous formations penetrated by the typical well in the Hari sag, and simulated the subsidence burial history of this well with software BasinMod. It is firstly pointed out that the tectonic subsidence evolution of the Hari sag since the Cretaceous can be divided into four phases: initial subsidence phase, rapid subsidence phase,uplift and erosion phase, and stable slow subsidence phase. A detailed reconstruction of the tectonothermal evolution and hydrocarbon generation histories of typical well was undertaken using the EASY R_0% model, which is constrained by vitrinite reflectance(R_0) and homogenization temperatures of fluid inclusions. In the rapid subsidence phase, the peak period of hydrocarbon generation was reached at c.a.105.59 Ma with the increasing thermal evolution degree. A concomitant rapid increase in paleotemperatures occurred and reached a maximum geothermal gradient of about 43-45℃/km. The main hydrocarbon generation period ensued around 105.59-80.00 Ma and the greatest buried depth of the Hari sag was reached at c.a. 80.00 Ma, when the maximum paleo-temperature was over 180℃.Subsequently, the sag entered an uplift and erosion phase followed by a stable slow subsidence phase during which the temperature gradient, thermal evolution, and hydrocarbon generation decreased gradually. The hydrocarbon accumulation period was discussed based on homogenization temperatures of inclusions and it is believed that two periods of rapid hydrocarbon accumulation events occurred during the Cretaceous rapid subsidence phase. The first accumulation period observed in the Bayingebi Formation(K_1 b) occurred primarily around 105.59-103.50 Ma with temperatures of 125-150℃. The second accumulation period observed in the Suhongtu Formation(K_1 s) occurred primarily around84.00-80.00 Ma with temperatures of 120-130℃. The second is the major accumulation period, and the accumulation mainly occurred in the Late Cretaceous. The hydrocarbon accumulation process was comprehensively controlled by tectono-thermal evolution and hydrocarbon generation history. During the rapid subsidence phase, the paleo temperature and geothermal gradient increased rapidly and resulted in increasing thermal evolution extending into the peak period of hydrocarbon generation,which is the key reason for hydrocarbon filling and accumulation.  相似文献   

河南塔山萤石矿地球化学特征及成矿年龄     

张凯涛 《地质与勘探》2023,59(2):236-247

为探究河南塔山萤石矿的成矿流体、成矿温度、成矿年龄及矿床成因,对研究区稀土元素、流体包裹体和Sm-Nd同位素特征进行了研究。研究区经历多期次的成矿作用,紫色萤石形成时间较早,紫色萤石成矿早期成矿流体中的稀土元素由吸附状态逐渐过渡到络合物状态,成矿晚期成矿流体中的稀土元素主要以络合物形式存在,为主成矿阶段,其球粒陨石标准化稀土元素配分模式和Y/Ho值与牛心山黑云母二长花岗岩、大理岩基本一致,指示三者之间有一定的成因联系。浅绿色萤石形成时间相对较晚,其与紫色萤石的稀土元素配分模式差异较大,表明二者具有不同成矿物质来源。塔山萤石矿发育气液两相包裹体,包裹体均一温度为143.6～168.5℃,盐度(NaCl_eqv)为7.02%～10.43%,密度为0.95～1.01 g/cm³;包裹体气-液相成分以H₂O为主,含有少量C₂H₆,成矿流体属于低温、中低盐度、低密度的NaCl-H₂O体系。测得的浅绿色萤石的成矿年龄为(141±13)Ma,为研究区萤石成矿年龄上限,推断...  相似文献   

Mineralization of the Liwu large-scale stratiform copper deposits in Sichuan Province,China: Constraints from fluid inclusions     

《China Geology》2023,6(2):252-268

The Liwu stratiform copper deposit is located in the northwestern Jianglang dome, western China. Current studies mainly focus on the genetic type and mineralization of this deposit. Detailed fluid inclusion characteristics of metallogenic period quartz veins were studied to reveal the ore-forming fluid features. Laser Raman analysis indicates that the ore-forming fluids is a H₂O-NaCl-CH₄ (-CO₂) system. Fluid inclusions microthermometry shows a homogenization temperature of 181–375°C and a salinity of 5.26%–16.99% for the disseminated-banded Cu-Zn mineralization; but a homogenization temperature of 142–343°C and a salinity of 5.41%–21.19% for the massive-veined Cu-Zn mineralization. These features suggest a medium-high temperature and a medium salinity for the ore-forming fluids. H-O isotopic data indicates that the ore-forming fluids were mainly from the metamorphic and magmatic water, plus minor formation water. And sulfur isotopic data indicates that sulfur was mainly derived from the formation and magmatic rocks. Metallogenesis of the disseminated-banded mineralization was mainly correlated with fluid mixing and water-rock reaction; whereas that of the massive-veined mineralization was mainly correlated with fluid boiling. The genetic type of the deposit is a medium-high temperature hydrothermal deposit related to magmatism and controlled by shear zones. This study is beneficial to understand the stratiform copper deposit.©2023 China Geology Editorial Office.  相似文献   

内蒙古迪彦钦阿木斑岩钼矿床成矿流体的出溶、演化及对成矿的制约     

崔凯  李腊梅  吴皓然  王兴源  王信  廉永  谢玉玲 《岩石矿物学杂志》2022,41(6):1120-1134

迪彦钦阿木钼矿床位于内蒙古东乌旗地区,矿区侵入岩不发育,主要为细粒正长岩和基性岩脉,矿体主要发育在侏罗纪火山岩中,少量发育在细粒正长岩中,主要矿化类型为细网脉状、脉状、浸染状,具有斑岩型矿化特征。矿区的细粒正长岩中可见含矿石英-钾长石囊团或由之构成中心相的热液脉体,是岩浆-流体转化过程的直接证据。本文在详细岩相学观察的基础上,对石英-钾长石囊团中主要组成矿物开展了阴极发光图像分析,对石英、萤石中流体包裹体开展了显微测温实验,并借助SEM/EDS、显微激光拉曼探针、LA-ICP-MS等手段对包裹体成分进行了系统分析,基于以上实验结果对岩浆流体的出溶过程、出溶流体特征及矿质沉淀机制进行了探讨。研究结果表明,矿区钼成矿与细粒正长岩岩浆出溶流体有关;富F和挥发分造成成矿岩浆具有低的固相线温度和较低的黏度,因此成矿岩浆可以沿断裂快速上侵到地壳浅部;岩浆上侵过程中的减压沸腾可能是流体出溶的主要机制;早期出溶流体为富F和富CO₂的中高温(227~457℃)、中低盐度[w(NaCl_eq)=0.3%～8.6%]流体,由于快速减压造成流体沸腾形成低盐度富CO₂的气相和高盐度液相,沸腾引起的CO₂逃逸可能是矿质沉淀的主要原因。  相似文献   

西昆仑沃克金矿床地质特征、金的赋存状态及矿床成因探讨     

冯京  徐仕琪  邓军  何福保  薛小龙  尹得功  薛春纪  郝延海  李平  赵同阳 《矿床地质》2022,41(3):623-642

沃克金矿床是西昆仑西段金铜矿带近期发现的一处具有大型远景的金矿床。金矿体主要产于近东西向展布的韧-脆性剪切带中,赋矿岩石为穿切于绢云千枚岩中的石英脉。主要矿化类型为毒砂矿化、黄铁矿化、黄铜矿化,热液蚀变为绢云母化、硬绿泥石化和碳酸盐化。在野外地质勘查与研究的基础上,笔者结合镜下显微观察,将成矿阶段划分为早（S1）、主（S2）和晚（S3）阶段,主阶段形成大量硫化物及方解石石英脉。载金硫化物主要为毒砂,次为黄铜矿、方铅矿。利用电子探针（EPMA）对载金硫化物进行分析,结合单元素面扫描成像,笔者认为金矿石主要以细粒金和中粒金形式存在。流体包裹体显示温度变化范围230~493℃,w （NaCl） _eq为1.56%~18.19%,成矿流体具有中高温、中低盐度的特征,表现为NaCl-H₂O-CO₂体系。石英δ¹⁸O值为8.6‰~14.0‰,流体的δD值在-83.7‰~-103.6‰,显示出变质水和大气降水的混合流体来源特征;硫同位素组成显示成矿物质源自中浅变质岩。笔者认为,沃克金矿床为与韧-脆性剪切带有关的中成造山型金矿床。  相似文献   

大兴安岭北部十五里桥金矿床流体包裹体特征及矿床成因     

孙彦峰  周传芳  王久懿  梁中恺  姜平  杜海双 《地质与资源》2022,31(5):606-613

十五里桥金矿床位于上黑龙江Au（Cu-Mo）成矿带内,上黑龙江盆地南缘、腰站断陷北缘与二十二站隆起南缘交接地带. 矿床可划分为4个成矿阶段：Ⅰ—脉状黄铁矿-石英阶段;Ⅱ—浸染状黄铁矿±黄铜矿-石英阶段;Ⅲ—浸染状黄铁矿±黄铜矿±闪锌矿±方铅矿-石英阶段;Ⅳ—少硫化物-碳酸盐阶段. 其中多金属硫化物-石英阶段为主成矿阶段. 流体包裹体研究表明,Ⅱ、Ⅲ阶段发育富气相和富液相型流体包裹体,Ⅱ阶段流体发生不混溶,均一温度介于283~394 ℃之间,盐度介于2.56%~7.99%（NaCl当量,质量分数）之间;Ⅲ阶段均一温度介于251~298 ℃,盐度介于2.56%~5.09%（NaCl当量,质量分数）,属于简单的NaCl-H₂O体系. H-O同位素指示成矿流体主要为大气降水;S同位素指示成矿物质主要来自深源岩浆硫. 十五里桥金矿床为火山岩容矿的浅成中温热液型矿床.  相似文献   

Genesis of the Maoling gold deposit in the Liaodong Peninsula: Constraints from a combined fluid inclusion,C-H-O-S-Pb-He-Ar isotopic and geochronological studies     

《地学前缘(英文版)》2022,13(4):101379

The large tonnage Maoling gold deposit (25 t @ 3.2 g/t) is located in the southwest Liaodong Peninsula, North China Craton. The deposit is hosted in the Paleoproterozoic metamorphic rocks. Four stages of mineralization were identified in the deposit: (stage I) quartz-arsenopyrite ± pyrite, (stage II) quartz-gold- arsenopyrite-pyrrhotite, (stage III) quartz-gold- polymetallic sulfide, and (stage IV) quartz-calcite-pyrrhotite. In this paper, we present fluid inclusion, C-H-O-S-Pb-He-Ar isotope data, zircon U-Pb, and gold-bearing sulfide (i.e. arsenopyrite and pyrrhotite) Rb-Sr age of the Maoling gold deposit to constrain its genesis and ore-forming mechanism. Three types of fluid inclusions were distinguished in quartz-bearing veins, including liquid-rich two-phase (WL type), gas-rich two-phase (GL type), and daughter mineral-bearing fluid inclusions (S type). Fluid inclusions data show that the homogenization at temperatures 197 to 372 °C for stage I, 126 to 319 °C for stage II, 119 to 189 °C for stage III, and 115 to 183 °C for stage IV, with corresponding salinities of 3.7 to 22.6 wt.%, 4.7 to 23.2 wt.%, 5.3 to 23.2 wt.%, and 1.7 to 14.9 wt.% NaCl equiv., respectively. Fluid boiling was the critical factor controlling the gold and associated sulfide precipitation at Maoling. Hydrogen and oxygen stable isotopic analyses for quartz yielded δ¹⁸O = ?5.0‰ to 9.8‰ and δ D = ?133.5‰ to ?77.0‰. Carbon stable isotopic analyses for calcite and ankerite yielded δ¹³C = ?2.3‰ to ?1.2‰ and O = 7.9‰ to 14.1‰. The C-H-O isotope data show that the ore-forming fluids were originated from magmatic water with meteoric water input during mineralization. Hydrothermal inclusions in arsenopyrite have ³He/⁴He ratios of 0.002 Ra to 0.054 Ra, and ⁴⁰Ar/³⁶Ar rations of 1225 to 3930, indicating that the ore-forming fluids were dominantly derived from crustal sources almost no mantle input. Sulfur isotopic values of Maoling fine-grained granite range from 6.‰1 to 9.8‰, with a mean of 7.7‰, δ³⁴S values of arsenopyrite from the mineralized phyllite (host rock) range from 8.9‰ to 10.6‰, with a mean of 10.0‰, by contrast, δ³⁴S values of sulfides from ore vary between 4.3‰ and 10.6‰, with a mean of 6.8‰, suggesting that sulfur was mainly originated from both the host rock and magma. Lead radioactive isotopic analyses for sulfides yielded ²⁰⁶Pb/²⁰⁴Pb = 15.830–17.103, ²⁰⁷Pb/²⁰⁴Pb = 13.397–15.548, ²⁰⁸Pb/²⁰⁴Pb = 35.478–36.683, and for Maoling fine-grained granite yielded ²⁰⁶Pb/²⁰⁴Pb = 18.757–19.053, ²⁰⁷Pb/²⁰⁴Pb = 15.596–15.612, and ²⁰⁸Pb/²⁰⁴Pb = 38.184–39.309, also suggesting that the ore-forming materials were mainly originated from the host rocks and magma. Zircon U-Pb dating demonstrates that the Maoling fine-grained granite was emplaced at 192.7 ± 1.8 Ma, and the host rock (mineralized phyllite) was emplaced at some time after 2065.0 ± 27.0 Ma. Arsenopyrite and pyrrhotite give Rb–Sr isochron age of 188.7 ± 4.5 Ma, indicating that both magmatism and mineralization occurred during the Early Jurassic. Geochronological and geochemical data, together with the regional geological history, indicate that Early Jurassic magmatism and mineralization of the Maoling gold deposit occurred during the subducting Paleo-Pacific Plate beneath Eurasia, and the Maoling gold deposit is of the intrusion-related gold deposit type.  相似文献   

广西佛子冲铅锌矿床闪锌矿铷锶同位素年代学研究   总被引：1，自引：0，他引：1  

罗俊华  张燕挥  翟丽娜  刘炜  江河 《化工矿产地质》2012,(1):26-31

佛子冲铅锌矿床位于钦-杭成矿带西南地段、博白-岑溪深断裂带北端。铅锌矿体产于奥陶系浅变质泥质灰岩中,严格受近北北东向断层和岩体与地层接触面控制。通过研究佛子冲铅锌矿床闪锌矿单矿物特征和稳定同位素研究,以及采用闪锌矿Rb-Sr同位素测年方法,测得佛子冲铅锌矿床成矿年龄为134.7±3.5Ma,认为该矿床的形成与燕山晚期岩浆、构造活动有关。硫、氢和氧组成及锶同位素初始比值测试结果表明佛子冲铅锌矿床成矿物质来源主要源自岩浆热液提供。  相似文献